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I am not sure what do you use the XmlDocument for. Do you mean that you are trying to read KML files? If this is your case the, you should be able to use the KmlReader class in code-behind as shown here: https://github.com/telerik/xaml-sdk/blob/master/Map/WPF/KMLManualReading/MainWindow.xaml.cs
If this is not your case, then can you provide more information about your exact setup?
I am not sure what do you use the XmlDocument for. Do you mean that you are trying to read KML files? If this is your case the, you should be able to use the KmlReader class in code-behind as shown here: https://github.com/telerik/xaml-sdk/blob/master/Map/WPF/KMLManualReading/MainWindow.xaml.cs
If this is not your case, then can you provide more information about your exact setup?