There is no out-of-the-box approach for expanding a ribbon group in all available space of its ribbon tab. However, you can achieve this with custom code. Basically you can create a custom groups panel that inherits the RibbonGroupsPanel and override its ArrangeOverride() method.
I also attached a sample project demonstrating this approach. Please give it a try and let me know if it works for you.
Regards,
Martin
Telerik
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