You can't do this since the WPF (and Silverlight) grid is virtualized using container recycling and cell value depends on the current grid horizontal and vertical scroll. If you post more info about your scenario I'll gladly help you.
All the best,
Vlad
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I have the same problem with Luis Tirado
My scenario is a gridview and textbox.
When I click a row in gridview i want the textbox show the value of that row (column 1)
I try this: textbox1.text=gridview1.selectedRow.column[1].tostring();
but it didtn work
So how can i do?