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This could be achieved with a ListView control that is data bound to the same collection as the ItemsSource of the PieSeries. You will have to set a custom ListView.ItemTemplate that contains color and information for the corresponding data point. If you create a custom chart palette
you will be able to get the right color for a data item depending on its index in the collection.
Unfortunately, at this moment there is a bug with the RadPieChart and the palettes are not applied properly to the series. We will look into this issue and will get back to you as soon as we have a solution.
I have attached a sample project that demonstrates how this it could work, but please note that only the pie chart in the Windows Phone project renders correctly.
I hope this helps.
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